Вопрос
[Cd(NH_(3))_(4)]Cl_(2);K_(2)[Cd(CN)_(4)] 2. Which of the above mentioned complexes is more stable? 3. Calculate the concentration of the Ag^+ ions in a 0 ,I M solution containing an excess of 1mol/l of NH_(3)
Решения
4.4
(251 Голоса)
Петр
Экспертная проверка
элита · Репетитор 8 лет
Ответ
1. The stability of the complexes
and
depends on the ligand field stabilization energy and the overall stability of the coordination compound. In general, the stability of a complex is influenced by factors such as the nature of the metal ion, the type of ligand, the coordination number, and the overall charge of the complex.2. To determine which of the two complexes is more stable, we need to consider the ligand field stabilization energy and the overall stability of the coordination compound. In general, the stability of a complex is influenced by factors such as the nature of the metal ion, the type of ligand, the coordination number, and the overall charge of the complex.3. To calculate the concentration of
ions in a 0.1 M solution containing an excess of 1 mol/L of
, we can use the solubility product constant (Ksp) for the precipitation of
.The solubility product constant (Ksp) for the precipitation of
is given by:Ksp = [Ag(NH3)2+] [NH3]^2Given that the concentration of
is in excess, we can assume that the concentration of
remains constant at 1 mol/L. Therefore, the concentration of
ions can be calculated as:[Ag+] = Ksp / [NH3]^2Substituting the given values, we have:[Ag+] = 1.8 x 10^-8 / (1)^2 = 1.8 x 10^-8 MTherefore, the concentration of
ions in the 0.1 M solution containing an excess of 1 mol/L of
is 1.8 x 10^-8 M.