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20. A+Barrow HCequiv CHxrightarrow [-Z](NaH)arrow A(CH_(3)I)/(-272)arrow B(NaNH_(3))/(-272)arrow Cxrightarrow [-2](CH_{2)I}arrow

Вопрос

20. A+Barrow HCequiv CHxrightarrow [-Z](NaH)arrow A(CH_(3)I)/(-272)arrow B(NaNH_(3))/(-272)arrow Cxrightarrow [-2](CH_(2)I)arrow (H_(2)O)/(H_(2)SO_(4))E

Решения

4.1 (194 Голоса)
Харитон
Экспертная проверка
элита · Репетитор 8 лет

Ответ

To determine the correct answer, let's analyze the given chemical reactions step by step:1. - This reaction involves the addition of sodium hydride (NaH) to acetylene (HC≡CH), resulting in the formation of acetylide ion (C2H−).2. - In this reaction, the acetylide ion (A) reacts with methyl iodide (CH3I) to form propyne (CH3C≡CH).3. - The propyne (B) reacts with sodium amide (NaNH3) to form propyne sodium salt (C).4. - The propyne sodium salt (C) reacts with methyl iodide (CH2I) to form 1-methylpropyne (D).5. - The 1-methylpropyne (D) undergoes hydrolysis in the presence of water (H2O) and sulfuric acid (H2SO4) to form 2-methylpropene (E).Therefore, the correct answer is E.